Thanks - he is a real personality.
I haven't been very well lately and am not expressing myself very well :(
I'll try again and take my time this time ;)
The fish has normal scales. The head has the normal plate -like areas that are not shaped like the small body scales but are mad up of the shame material. This part of his body has no pigment cells and no guanine layer so no colour and no metallic shine - just see through.
All fish scales are transparent. They have no colour. So what matters is what is under the scales.
Under the scales (and on the fins and tail) there are pigment cells - melanophores: black (melanin); erythrophores: red (pteridines and carotenids); xanthophores: yellow (carotenids)
Also under the scales there can be a guanine layer with 2 different types of cell - leucophores with small crystals of guanine and iridophores with large crystals. The large crystals are more reflective.
Depending on which and how many of these cells the fish has the fish will be either shiny and reflective (ie meatallic) or pearl or, if it has none, matt.
A white or silver white fish has no pigment but has plenty of guanine. The larger the crystals the more metallic looking the fish is.
So using my fish as an example: His body has has erythrophores and xanthophores in the red areas, no pigment cells in the white areas but he has a guanine layer all over his body(reflection but no colour).
But his head has no pigment cells and no guanine layer - like a "pink" (albino) fish so you can just see through it. I have to admit he is the only goldfish I have seen with no colour or guanine on its head. I have seen a koi with about the front third of its head transparent though.
He has no melanophores. He did when he was a baby. Except for albinos all gold fish are born with melanophores but those cells tend to die and not replace themselves. They usually get replaced with other colours. If not the area turns white. If they are replaced by orange the area may stay orange but it is also possible for those pigment cells to die and leave the area white. Which is why gold fish change colours.
One of my baby goldfish in the quarantine pond lost all its melanophores before it was even an inch long and is now a lovely pale shiny yellow orange. It only just big enough for me to see that cute little black mustache they have before the last of the black disappears.
This is a really interesting article on colour change in goldfish if anyone is interested in that topic.
http://thegab.org/Articles/ColorChange.html