Mister Bullfrog, I have a few questions.
You had just the number two of toad tadpoles? If so, they would hardly result in problems with high ammonia or low oxygen in a 500 gallon pond. Or, were there a lot of toad eggs and tadpoles? One egg laying is normally hundreds of toads. If the pond is not properly aerated and filtered or too small, then the ammonia may spike and/or the oxygen go down.
How did you test for said "biotoxins?" What exactly are we talking about? Just ammonia? That's inorganic (not a biotoxin).
Good aeration and filtration as well as doing water changes and adding carbon to the pond may have all helped. Removal of some of the toad eggs and tadpoles to another pond would also reduce the impact.
Your two goldfish are both still alive, right? So, they weathered the Bufo storm.
My toad page has more information -
http://www.fishpondinfo.com/toad.htm